What model Acer do you have? In my C102ti and probably most Acer's you'd do the following;
Go to Start > All Programs > Launch Manager, when you click on Launch Manager you'll get a window that will allow you to program all four buttons actually.
I have P1 set to open Word and P2 set to open Excell, you do that by clicking on add and going to folder that has the program you want to customize and clicking on it.
Otherwise go to your users manual, it should give you fairly clear instructions of how to customize your Launch Manager.
;)




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